The Valdelacasa anticlinorium includes in its core Ediacaran-Lower Cambrian materials belonging, palaeogeographically, to two sectors which represented, at the end of the Ediacaran, the transition between a shallow carbonate platform environment and the deeper environments of the slope to the north, the only area which still included marine environments in the Early Cambrian, and which emerged at the beginning of the Middle Cambrian.
On the southwestern flank of this large megastructure are the carbonate materials of the Ibor Group (Peraleda de San Román area). On the northeastern flank we find the Cíjara Formation, consisting of shales, greywackes (sometimes very sandy) and conglomerates with abundant phosphate clasts. This unit includes numerous sedimentary structures and ichnofossils that indicate transitional environments from the upper part of a slope to a distal platform.
Discordant over these materials are olistostromic formations, which are the result of the collapse of the carbonate platforms of the Ibor Group due to the steep inclination of the slopes, in unstable environments with high seismicity, related to the final phases of the Cadomian Orogeny. The carbonate blocks of the olistostroma of the Pedroso stream, located in the north of the geopark, include specimens of Cloudina.
These materials are followed by an important Lower Cambrian succession that records “the great biotic radiation of the Cambrian”, and includes in areas very close to the Geopark, in the province of Toledo, deposits of the oldest trilobites and archaeocyaths in the Iberian Peninsula. All these sedimentary materials are intruded by granitic materials, which is why it is common to come across berrocales (landscapes with an abundance of stones and granitic boulders) which sometimes leave figures of great scenic and geological value, such as those studied in the “desfiladero de Pedroso” and “berrocal de Peraleda-Cancho Valdecastillo” geosites.
This megastructure is approximately one hundred kilometres long and several kilometres wide and runs in a NW-SE direction. It is bounded to the west by the outcrops of Lower Palaeozoic rocks that make up the Guadarranque syncline, while to the north, east and south its limits are less clear, with outcrops of Palaeozoic rocks alternating with Cenozoic sedimentary materials (rañas).